Strong heat source at the isolation condenser wall of an Advanced Heavy Water Reactor, results in natural convection in gravity driven water pool, which leads to a thermally stratified pool. Governing equations simulating fluid flow and heat distribution are solved numerically by a general purpose Computational Fluid Dynamics solver developed at Indian Institute of Technology, Kanpur. Incompressible finite volume method with non-staggered grid arrangement is used in this exercise. This algorithm is fully implicit and semi-coupled. Turbulent natural convection in a boundary layer for high Rayleigh numbers is analyzed by the Lam-Bremhorst k - ε turbulence model. Analysis of unsteady laminar natural convection in a side-heated water cavity is also done for different values of Rayleigh number. Results show a warm fluid layer floating on the top of gradually colder layer (along the vertical direction) that indicates the presence of thermal stratification phenomenon. This fact necessitates additional safety features in such a system so that the detrimental effect such as stratification is minimized. © 2008 Springer-Verlag.