The sterically encumbered β-diketiminate bismuth(III) bistriflate, LBi(OSO 2CF 3) 2 [L = HC{(CMe)N(2, 6-iPr 2C 6H 3)} 2] (2) was prepared from a facile one-pot reaction between potassium β-diketiminate LK (1) and bismuth(III) triflate. It was characterized by elemental analysis, FT-IR, 1H NMR, 13C NMR, and 19F NMR spectroscopy. The molecular structure of 2 was further confirmed by single-crystal X-ray crystallography. The solid-state structure of 2 reveals a first structurally characterized monomeric β-diketiminate supported group 15 bistriflate. The coordination number of bismuth is four. Copyright © 2012 WILEY-VCH Verlag GmbH &amp; Co. KGaA, Weinheim.

Prabusankar Ganesan

Department of Chemistry

P. Suresh

A. Sathyanarayana

O. Hernandez

S. Golhen

Indian Institute of Technology Hyderabad (IITH) is a premier institute of science and technology established in 2008. IITH has been consistently ranked in the&nbsp;<a href="https://iith.ac.in/reports/" rel="noopener noreferrer">top 10 institutes</a>&nbsp;in India for Engineering&nbsp;<a href="https://www.nirfindia.org/2021/EngineeringRanking.html" rel="noopener noreferrer" target="_blank">according to NIRF</a>&nbsp;making it one of the most coveted schools for science and technology in the country.

IITH offers&nbsp;<a href="https://iith.ac.in/academics/under-graduate/">undergraduate programs</a>&nbsp;in all the classical engineering disciplines, applied sciences, design, as well as several modern interdisciplinary areas. Students are given a flexibility to explore a broad set of areas, and potentially pursue a minor or double major in a discipline that is not their own. Students who wish to seek a deeper understanding of their own discipline are strongly encouraged to get involved in cutting-edge research with the help of a faculty to mentor them, and earn an Honors in their own field.

The very foundation of IIT Hyderabad is based on&nbsp;<a href="https://iith.ac.in/research/">research and innovation</a>. The vibrant research culture is evident from the number of patents and publications that IITH produces consistently every year. IITH offers&nbsp;<a href="https://iith.ac.in/academics/programmes-offered/">graduate programs</a>&nbsp;at both a masters, and a doctoral level, in several diverse areas. There are separate programs for technology, design, science, and liberal arts. The&nbsp;<a href="https://iith.ac.in/academics/post-graduate/">MTech program</a>&nbsp;is offered in various modes and durations to cater to the ever-growing need of postgraduate level professionals in the country.

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Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
ISSN	00442313