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Temperature effects for crystal growth: A distribution kinetics approach
, B.J. McCoy
Published in
2003
Volume: 51
   
Issue: 7
Pages: 2031 - 2040
Abstract
The effect of temperature on the growth and dissolution dynamics of nonequilibrium crystal size distributions can be determined by solving the governing population balance equations. The model includes the effect of temperature through the diffusion-influenced growth coefficient, the phase transition energy, and the Gibbs-Thomson effect of particle curvature and interfacial energy. The time evolution of the average size of two polymorphs evolving from a single solute is also modeled. We show that the average sizes of the two polymorphs diverge, one continuing to increase, the other decreasing with time, indicating dynamic ripening. Strategies that allow temperature programming suggest how competing crystal or grain growth processes can be controlled. © 2003 Acta Materialia Inc. Published by Elsevier Science Ltd. All rights reserved.
About the journal
JournalActa Materialia
ISSN13596454