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Synthesis and electrochemical properties of substituted para-benzoquinone derivatives
, S. Choudhury
Published in
2010
Volume: 51
   
Issue: 18
Pages: 2541 - 2544
Abstract
A facile transformation of pentasubstituted tribromophenol derivatives to the corresponding alkyl-substituted dibromo-p-benzoquinones has been achieved using PbO2 as oxidizing agent in combination with 60% aq HClO4 in acetone in 70-72% yields. The electrochemical properties of these quinones were studied by means of cyclic voltammetry and compared with p-benzoquinone (BQ) and 2,3-dichloro-5,6-dicyano-benzoquinone (DDQ) recorded under identical experimental conditions. © 2010 Elsevier Ltd. All rights reserved.
About the journal
JournalTetrahedron Letters
ISSN00404039