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Study of Thermal Relaxation of Poly (HDDA-co-MMA) by Temperature Modulated DSC and Dielectric Spectroscopy
A. Goswami, A.M. Umarji,
Published in
2013
Volume: 52
   
Issue: 5
Pages: 485 - 494
Abstract
The thermal transitions in the copolymer of 1,6-hexanediol diacrylate (HDDA) and methyl methacrylate (MMA) was investigated to understand its use in microstereolithography. The glass transition temperature and the effect of interaction on this transition process was investigated by means of temperature modulated differential scanning calorimetry (TMDSC). The heat capacities were determined and PHDDA rich phases showed lower heat capacity than PMMA rich phases. The frequency dependence of glass transitions were studied by varying the modulation period of TMDSC and confirmed by dielectric relaxation spectroscopy. Vogel Fulcher Tammann Hesse (VFTH) parameters of homo and copolymers have also been reported. © 2013 Copyright Taylor and Francis Group, LLC.
About the journal
JournalPolymer - Plastics Technology and Engineering
ISSN03602559