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Strain-mediated ferromagnetism and low-field magnetic reversal in Co doped monolayer WS2
A.K. Jena, S.K. Mallik, M.C. Sahu, S. Sahoo, A.K. Sahoo, N.K. Sharma, , S.K. Gupta, R. Ahuja, S. Sahoo
Published in Nature Research
2022
PMID: 35173206
Volume: 12
   
Issue: 1
Abstract
Strain-mediated magnetism in 2D materials and dilute magnetic semiconductors hold multi-functional applications for future nano-electronics. Herein, First principles calculations are employed to study the influence of biaxial strain on the magnetic properties of Co-doped monolayer WS2. The non-magnetic WS2 shows ferromagnetic signature upon Co doping due to spin polarization, which is further improved at low compressive (-2 %) and tensile (+2 %) strains. From the PDOS and spin density analysis, the opposite magnetic ordering is found to be favourable under the application of compressive and tensile strains. The double exchange interaction and p-d hybridization mechanisms make Co-doped WS2 a potential host for magnetism. More importantly, the competition between exchange and crystal field splittings, i.e. (Δ ex> Δ cfs), of the Co-atom play pivotal roles in deciding the values of the magnetic moments under applied strain. Micromagnetic simulation reveals, the ferromagnetic behavior calculated from DFT exhibits low-field magnetic reversal (190 Oe). Moreover, the spins of Co-doped WS2 are slightly tilted from the easy axis orientations showing slanted ferromagnetic hysteresis loop. The ferromagnetic nature of Co-doped WS2 suppresses beyond ±2% strain, which is reflected in terms of decrease in the coercivity in the micromagnetic simulation. The understanding of low-field magnetic reversal and spin orientations in Co-doped WS2 may pave the way for next-generation spintronics and straintronics applications. © 2022, The Author(s).
About the journal
JournalScientific Reports
PublisherNature Research
ISSN20452322