The facile method of solution combustion was used to synthesize γ(L)-Bi2MoO6. The material was crystallized in a purely crystalline orthorhombic phase with sizes varying from 300 to 500 nm. Because the band gap was 2.51 eV, the degradation of wide variety of cationic and anionic dyes was investigated under solar radiation. Despite the low surface area (<1 m2/g) of the synthesized material, γ(L)-Bi 2MoO6 showed high photocatalytic activity under solar radiation due to its electronic and morphological properties. © 2011 Elsevier Ltd. All rights reserved.