(Chemical Equation Presented) The reduction of SnCl2 by the low-valent gallium(I) β-diketiminate GaI(ddp) gives the title complex, which is best described as a Zintl-type anionic [Sn17] 4- cluster stabilized by an electrophilic shell of gallium ligands. This reaction could represent a new concept for the synthesis of metalloid main-group clusters. ddp = HC(CMeNC6H3-2,6-iPr 2)2. © 2008 Wiley-VCH Verlag GmbH &amp; Co. KGaA.

Prabusankar Ganesan

Department of Chemistry

A. Kempter

C. Gemel

M.-K. Schöter

R.A. Fischer

Indian Institute of Technology Hyderabad (IITH) is a premier institute of science and technology established in 2008. IITH has been consistently ranked in the&nbsp;<a href="https://iith.ac.in/reports/" rel="noopener noreferrer">top 10 institutes</a>&nbsp;in India for Engineering&nbsp;<a href="https://www.nirfindia.org/2021/EngineeringRanking.html" rel="noopener noreferrer" target="_blank">according to NIRF</a>&nbsp;making it one of the most coveted schools for science and technology in the country.

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Journal	Angewandte Chemie - International Edition
ISSN	14337851