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Simple three parameter equations for correlating liquid phase compositions in subcritical and supercritical systems
R.C. Narayan,
Published in Elsevier B.V.
2014
Volume: 95
   
Pages: 100 - 105
Abstract
Two Chrastil type expressions have been developed to model the solubility of supercritical fluids/gases in liquids. The three parameter expressions proposed correlates the solubility as a function of temperature, pressure and density. The equation can also be used to check the self-consistency of the experimental data of liquid phase compositions for supercritical fluid-liquid equilibria. Fifty three different binary systems (carbon-dioxide + liquid) with around 2700 data points encompassing a wide range of compounds like esters, alcohols, carboxylic acids and ionic liquids were successfully modeled for a wide range of temperatures and pressures. Besides the test for self-consistency, based on the data at one temperature, the model can be used to predict the solubility of supercritical fluids in liquids at different temperatures. © 2014 Elsevier B.V. All rights reserved.
About the journal
JournalData powered by TypesetJournal of Supercritical Fluids
PublisherData powered by TypesetElsevier B.V.
ISSN08968446