Rhenium(i)-based supramolecular coordination complexes were obtained using Re2 (CO)10 , (2-hydroxyphenyl)benzimidazole-derived bis-chelating N?O donors and a benzimidazolyl-derived ditopic monodentate N-donor possessing Troger's base spacer in a one-pot approach. © Schweizerische Chemische Gesellschaft.