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Reversible swelling/deswelling characteristics of ethylene glycol dimethacrylate cross-linked poly(acrylic acid-co-sodium acrylateco-acrylamide) superabsorbents
N.B. Shukla,
Published in
2011
Volume: 50
   
Issue: 19
Pages: 10918 - 10927
Abstract
Poly(acrylic acid-co-sodium acrylate-co-acrylamide) superabsorbent polymers (SAPs) cross-linked with ethylene glycol dimethacrylate (EGDMA) were synthesized by inverse suspension polymerization. The SAPs were swollen inDI water, and it was found that the equilibrium swelling capacities varied with the acrylamide content. The SAPs were subjected to reversible swelling/deswelling cycles in DI water and aqueous NaCl solution, respectively. The effect of the addition of an electrolyte on the swelling of the SAP was explored. The equilibrium swelling capacity of the SAPs was found to decrease with increasing concentration of added electrolyte in the swelling medium. The effect of the particle size of the dry SAPs on the swelling properties was also investigated. A first order model was used to describe the kinetics of swelling/deswelling, and the equilibrium swelling capacity, limiting swelling capacity, and swelling/deswelling rate coefficients were determined. © 2011 American Chemical Society.
About the journal
JournalIndustrial and Engineering Chemistry Research
ISSN08885885