Fused heterocyclic compounds with alkyne substituent, have been achieved using a domino microwave-assisted [Pd]-catalysis. Interestingly, tert-propargyl alcohols underwent a selective degradative β-carbon cleavage and served as masked alkynyl equivalents, in water as the sole reaction medium. Dihydrobenzofurans, indolines, and oxindoles have been accomplished using this dual C–C bond-forming strategy. © 2020 Elsevier B.V.