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Pressure induced valence change of Eu in EuFe2As2 at low temperature and high pressures probed by resonant inelastic x-ray scattering
R.S. Kumar, Y. Zhang, A. Thamizhavel, A. Svane, G. Vaitheeswaran, , Y. Xiao, P. Chow, C. Chen, Y. Zhao
Published in
2014
Volume: 104
   
Issue: 4
Abstract
The effect of pressure on the valence state of Eu in EuFe 2As2 has been investigated at high pressures up to 43 GPa at 10 K using resonant inelastic x-ray scattering and x-ray absorption spectroscopy using partial fluorescence yield. Two distinct density functional approaches have been used to complement the experiments. Our experimental results show that the Eu valence increases from a divalent state to a nearly trivalent state under application of pressure in consistence with theoretical simulations. Furthermore, our calculations show that the Eu magnetic moments prevail at high pressure up to 45 GPa. © 2014 AIP Publishing LLC.
About the journal
JournalApplied Physics Letters
ISSN00036951