We study the phenomenology of a particular leptoquark extension of the Standard Model (SM), namely the doublet-singlet scalar leptoquark extension of the SM (DSL-SM). Besides generating Majorana mass for neutrinos, these leptoquarks contribute to muon and electron (g-2) and various lepton flavor violating processes. Collider signatures of the benchmark points (BPs), consistent with the neutrino oscillation data, anomalous muon/electron magnetic moments, experimental bounds on the charged lepton flavor violation observables, etc., are studied at the LHC/FCC with center-of-mass energies of 14, 27 and 100 TeV. While the two-1/3 charged colored scalars from the singlet and the doublet leptoquark mix with each other, the charge 2/3 colored scalar from the doublet leptoquark remains pure. With a near-degenerate mass spectrum, the pure and mixed leptoquark states are shown to be distinguishable from multiple final states, while discerning between the two mixed states remains very challenging. © 2022 authors. Published by the American Physical Society. Published by the American Physical Society under the terms of the "https://creativecommons.org/licenses/by/4.0/"Creative Commons Attribution 4.0 International license. Further distribution of this work must maintain attribution to the author(s) and the published article's title, journal citation, and DOI. Funded by SCOAP3.