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Palladium-catalyzed carbonylations of aryl bromides using paraformaldehyde: Synthesis of aldehydes and esters
Dumrath Dr., Neumann Dr., Beller M.,
Published in Wiley-VCH Verlag
2014
Volume: 53
   
Issue: 38
Pages: 10090 - 10094
Abstract
Carbonylation reactions represent useful tools for organic synthesis. However, the necessity to use gaseous carbon monoxide is a disadvantage for most organic chemists. To solve this problem, novel protocols have been developed for conducting palladium-catalyzed reductive carbonylations of aryl bromides and alkoxycarbonylations using paraformaldehyde as an external CO source (CO gas free). Hence, aromatic aldehydes and esters were synthesized in moderate to good yields. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
About the journal
JournalData powered by TypesetAngewandte Chemie - International Edition
PublisherData powered by TypesetWiley-VCH Verlag
ISSN14337851
Open AccessNo