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Oxygen as moderator in the zinc-mediated reduction of aromatic nitro to azoxy compounds
, Ch. Sudheer
Published in
2009
Volume: 50
   
Issue: 26
Pages: 3394 - 3396
Abstract
A simple and useful protocol for the reduction of nitro arenes to their corresponding azoxy derivatives by employing zinc and NH4Cl in a mixture of [bmim][BF4] and water is described. The selective reduction of nitro to azoxy is attributed to the hitherto unknown moderating effect of oxygen on zinc metal. © 2009 Elsevier Ltd. All rights reserved.
About the journal
JournalTetrahedron Letters
ISSN00404039