An asymmetric erbium(iii) Schiff base complex [Er(HL)2(NO3)3] was synthesized which shows SMM behaviour with an Ueff of 5.2 K. Dipolar interaction in 1 significantly reduced upon dilution which increases the barrier height to 51.5 K. Ab initio calculations were performed to shed light on the mechanism of magnetization relaxation. © The Royal Society of Chemistry 2015.

Saurabh Kumar Singh

Department of Chemistry

C. Das

A. Upadhyay

S. Vaidya

G. Rajaraman

M. Shanmugam

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IIT Hyderabad

Chemical Communications

Origin of SMM behaviour in an asymmetric Er(iii) Schiff base complex: A combined experimental and theoretical study

Journal	Data powered by TypesetChemical Communications
Publisher	Data powered by TypesetRoyal Society of Chemistry
ISSN	13597345