Here we report a facile one-step solid-state synthesis of novel β-NaFeO2 nanopebble as a promising cathode material for sodium ion batteries (SIBs). The presence of octahedral sites at the β phase NaFeO2 enhances the cyclic performance of SIB via Fe3+/Fe4+ redox couple mechanism throughout the sodiation/desodiation cycles. The β-NaFeO2 exhibits a high specific discharge capacity (335 mAhg−1 at a rate of 0.1C for the 1st cycle and 136 mAhg−1 for the 150th cycle with 88.6% coulombic efficiency), rapid sodiation/desodiation kinetics with high sodium storage capability and excellent cyclability. The performance of the as-fabricated SIB with high specific capacity and good rate capability testify its potential application as a low cost, new cathode material for high-capacity SIBs. © 2020 Elsevier B.V.