Computational fluid dynamics simulations of fixed-bed adiabatic adsorption/desorption processes are presented in this paper. Linear driving force model is used for heat and mass transfer rates. A two-dimensional cylindrical canister and three-dimensional automotive production canister geometry are used to study the adsorption/desorption processes of carbon dioxide in helium carrier gas on Norit B4 activated carbon. The two-dimensional results compare well with the results of Hwang et al. [1]. Computational results as breakthrough curve, adsorption amount and temperature profiles are provided. Results show that non-adiabatic model should be used to fully utilize the activated carbon bed capacity prior to breakthrough. Copyright © 2003 SAE International.