Bis(phosphinimino)methanides exhibit a wide variety of coordination chemistry with almost all elements in the periodic table. This critical review deals with the chemistry and coordination behavior of bulky monoanionic (CH(PPh2NR)2)−bis(phosphinimino)methanide and dianionic (C(PPh2NR)2)2−bis(phosphinimino)methanediide (R = SiMe3, aryl) ligands focusing on s- and p-block as well as transition metals (109 references). © 2009 The Royal Society of Chemistry.

Tarun Kanti Panda

Department of Chemistry

P.W. Roesky

Indian Institute of Technology Hyderabad (IITH) is a premier institute of science and technology established in 2008. IITH has been consistently ranked in the&nbsp;<a href="https://iith.ac.in/reports/" rel="noopener noreferrer">top 10 institutes</a>&nbsp;in India for Engineering&nbsp;<a href="https://www.nirfindia.org/2021/EngineeringRanking.html" rel="noopener noreferrer" target="_blank">according to NIRF</a>&nbsp;making it one of the most coveted schools for science and technology in the country.

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Journal	Chemical Society Reviews
ISSN	03060012