Large eddy simulations (LESs) of turbulent horizontal buoyant jets are carried out using a high-order numerical method and Sigma subgrid-scale (SGS) eddy-viscosity model, for a number of different Reynolds (Re) and Richardson (Ri) numbers. Simulations at previous experimental flow conditions (Re = 3200, 24, 000 and Ri = 0, 0.01) are carried out first, and the results are found to be qualitatively and quantitatively similar to the experimental results, thus validating the numerical methodology. The effect of varying Ri (values 2 × 10-4, 0.001, 0.005, and 0.01) and Re (3200 and 24, 000) is studied next. The presence of stable stratification on one side and unstable stratification on the other side of the jet centreline leads to an asymmetric development of horizontal buoyant jets. It is found that this asymmetry, the total radial spread and the vertical deflection are significantly affected by Ri, while Re affects only the radial asymmetry. The need for developing improved integral models, accounting for this asymmetry, is pointed out. Turbulent production and dissipation rates are investigated, and are found to be symmetric in the horizontal plane, but asymmetric in the mid-vertical plane. A previously proposed model, for correlation between the vertical component of the fluctuating scalar flux vector and the vertical cross-correlation component of the Reynolds tensor, is modified based on the current LES results. Instantaneous scalar and velocity fields are analysed to reveal the structure of horizontal buoyant jets. Similar to the developed turbulent jet, the flow close to the nozzle too is found to be markedly different in the stable and unstable stratification regions. Persistent coherent vortex rings are found in the stable stratification region, while intermittent breakdown of vortex rings into small-scale structures is observed in the unstable stratification region. Similarities and differences between the flow structures in the horizontal buoyant jet configuration and those in the jet in crossflow configuration are discussed. Finally, a dynamic mode decomposition analysis is carried out, which indicates that the flow in the unstable stratification region is more energetic and prone to instabilities, as compared to the flow in the stable stratification region. © 2015 Taylor & Francis.