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Kinetics of the decomposition of hydrogen sulfide in a dielectric barrier discharge reactor
E. Linga Reddy, J. Karuppiah, A. Renken, L. Kiwi-Minsker,
Published in
2012
Volume: 35
   
Issue: 11
Pages: 2030 - 2034
Abstract
Kinetics of hydrogen sulfide (H2S) decomposition to hydrogen and sulfur was investigated in a nonthermal plasma dielectric barrier discharge (NTP-DBD) reactor operated under ambient conditions. The reactions were carried out with a fixed flow rate and varying inlet concentration. The results indicated that the dissociation of H2S into H2 and S may be initiated by excitation of the carrier gas argon. A reaction rate model based on a Langmuir Hinshelwood/Michaelis-Menten model was proposed. The formal reaction order approaches zero at high H2S concentrations. The parameters of the kinetic model were found to be dependent on the power input. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
About the journal
JournalChemical Engineering and Technology
ISSN09307516