In this article we report our experimental results on non collinear four-wave mixing (FWM) at air-dielectric interfaces. We generated FWM signal from the two interfaces of a 1mm thick fused silica slide with air using two 800 nm, 100 fs pump pulses in non-collinear pump-probe type geometry. We observe that there is a maximum peak shift of ∼1.5 nm in FWM signals corresponding to the two interfaces of the same silica slide. Further, we find that the intensity of FWM signal observed at air to silica interface is less than that from silica to air interface. We briefly elaborate on this observation with systematic study of FWM in fused silica. © 2008 Optical Society of America.