In this letter, we present a facile approach to fabricate hydrophobic surfaces based on electrostatic field assisted self-assembly of fibers onto conductive micropillars. Hydrophobic patterns fabricated in this work are inspired by an underwater fern Salvinia molesta. Hydrophilic cellulose acetate nanofibers were electrospun on a conducting micro-patterned surface to create a hierarchical structure. The water contact angle increased from just below 70° (hydrophilic) on the micro-patterned structures to ∼140° (hydrophobic) for the hierarchical structures. Introduced hydrophobicity is due to the pinning of the water droplet to suspended hydrophilic nanofibers and a reduced solid-water interface. © 2017 Elsevier B.V.