Field induced single-molecule-magnet behaviour is observed for both a heterodinuclear [ZnDy(L-)2]3+ complex (1) and a mononuclear [Dy(HL)2]3+ complex (2), with effective energy barriers of 83 cm-1 and 16 cm-1, respectively. Insights into the relaxation mechanism(s) and barrier heights are provided via ab initio and DFT calculations. Our findings reveal an interesting observation that the Ueff of SMMs can be enhanced by incorporating diamagnetic metal ions. This journal is © the Partner Organisations 2014.

Saurabh Kumar Singh

Department of Chemistry

A. Upadhyay

C. Das

R. Mondol

S.K. Langley

K.S. Murray

G. Rajaraman

M. Shanmugam

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Chemical Communications

Enhancing the effective energy barrier of a Dy(iii) SMM using a bridged diamagnetic Zn(ii) ion

Journal	Data powered by TypesetChemical Communications
Publisher	Data powered by TypesetRoyal Society of Chemistry
ISSN	13597345