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Enantiospecific approaches to bicyclic vibsanes: a ring-closing metathesis reaction-based strategy to functionalized bicyclo[4.3.1]decanes
A. Srikrishna, V.H. Pardeshi,
Published in
2008
Volume: 19
   
Issue: 16
Pages: 1984 - 1991
Abstract
An enantiospecific synthesis of functionalized bicyclo[4.3.1]decane, the bicyclic core system present in some bi- and tricyclic vibsane diterpenoids, for example, vibsanin E, via an RCM reaction of 2,6-diallylcarvone derivatives is described. It has been further extended to the synthesis of tricyclo[6.4.1.01,5]tridecanes starting from 2,6,6-triallylcarvones. © 2008 Elsevier Ltd. All rights reserved.
About the journal
JournalTetrahedron Asymmetry
ISSN09574166