Header menu link for other important links
X
Comparative study on sintering kinetics of as-milled and annealed CoCrFeNi high entropy alloy powders
Published in Elsevier Ltd
2018
Volume: 210
   
Pages: 49 - 56
Abstract
This work attempts to understand the effect of initial conditions, i.e., as-milled powder and phase stabilized nearly single phase powder (through annealing), on sintering kinetics of CoCrFeNi high entropy alloy powders. Dilatometric study indicates, axial shrinkage reduced from about 5% to 3% when powder was annealed. Analysis of shrinkage through non-isothermal method shows activation energies of sintering increased significantly for a given model, in annealed powder compared to as-milled powder. Calculated activation energies indicate, in as-milled powder grain boundary diffusion seems to be the dominating mechanism, attributed to the presence of ultrafine grains and a large fraction of grain boundaries. On the other hand, annealing helped to form almost single phase HEA, decrease in defect concentration and reduced grain boundary fraction with increased crystallites; which led to increase in activation energies. Coefficients of thermal expansion have also been studied and it was found to vary with temperature range. © 2017 Elsevier B.V.
About the journal
JournalData powered by TypesetMaterials Chemistry and Physics
PublisherData powered by TypesetElsevier Ltd
ISSN02540584