The first sterically controlled oxidation of mesoionic selone using copper(II) salt was demonstrated. The present methodology gave access to a rare tetraselenide from dimerized diselenides through chalcogen bonding (ChB). Besides, a similar approach with sterically less crowded mesoionic triazole selone, 1-(2-mesitylene)-3-methyl-4-phenyltriazolin-5-selone, gave the classic diselenide salt. In the solid state, these new selenide salts demonstrate a unique structural aggregation with unusual bonding features such as Se···O and Se···F interactions. © 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

Prabusankar Ganesan

Department of Chemistry

M. Vaddamanu

Indian Institute of Technology Hyderabad (IITH) is a premier institute of science and technology established in 2008. IITH has been consistently ranked in the&nbsp;<a href="https://iith.ac.in/reports/" rel="noopener noreferrer">top 10 institutes</a>&nbsp;in India for Engineering&nbsp;<a href="https://www.nirfindia.org/2021/EngineeringRanking.html" rel="noopener noreferrer" target="_blank">according to NIRF</a>&nbsp;making it one of the most coveted schools for science and technology in the country.

IITH offers&nbsp;<a href="https://iith.ac.in/academics/under-graduate/">undergraduate programs</a>&nbsp;in all the classical engineering disciplines, applied sciences, design, as well as several modern interdisciplinary areas. Students are given a flexibility to explore a broad set of areas, and potentially pursue a minor or double major in a discipline that is not their own. Students who wish to seek a deeper understanding of their own discipline are strongly encouraged to get involved in cutting-edge research with the help of a faculty to mentor them, and earn an Honors in their own field.

The very foundation of IIT Hyderabad is based on&nbsp;<a href="https://iith.ac.in/research/">research and innovation</a>. The vibrant research culture is evident from the number of patents and publications that IITH produces consistently every year. IITH offers&nbsp;<a href="https://iith.ac.in/academics/programmes-offered/">graduate programs</a>&nbsp;at both a masters, and a doctoral level, in several diverse areas. There are separate programs for technology, design, science, and liberal arts. The&nbsp;<a href="https://iith.ac.in/academics/post-graduate/">MTech program</a>&nbsp;is offered in various modes and durations to cater to the ever-growing need of postgraduate level professionals in the country.

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Journal	European Journal of Inorganic Chemistry
Publisher	Wiley-VCH Verlag
ISSN	14341948