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A novel dimeric copper salicylate with an undissociated COOH group: Synthesis and crystal structure of [Cu2(HSal)(Sal)(2,2′-bpy)2](ClO4)
N. Palanisami, , R. Murugavel
Published in
2006
Volume: 9
   
Issue: 10
Pages: 1002 - 1006
Abstract
A dinuclear copper salicylate [Cu2(HSal)(Sal)(2,2′-bpy)2](ClO4) (1) (H2Sal = salicylic acid) has been synthesized and characterized with the aid of elemental analysis and infrared, ultraviolet and fluorescence spectroscopic studies. The molecular structure of 1, determined by single-crystal X-ray diffraction studies, shows the presence of incompletely deprotonated salicylate ligands in the complex. Hydrogen bonding interactions and π-π aromatic stacking lead to the formation of 2D polymeric structure in the solid state. © 2006 Elsevier B.V. All rights reserved.
About the journal
JournalInorganic Chemistry Communications
ISSN13877003