A mesoionic N-heterocyclic carbene-gold(i) complex with a unique Au⋯H-C(methine) intramolecular hydrogen bonding interaction has been investigated in the solid state. The structure of this new neutral gold(i)-carbene was characterized by FT-IR and NMR spectroscopy, TGA, and X-ray diffraction techniques. Density functional theory (DFT) and atoms-in-molecule (AIM) analysis revealed that the gold-hydrogen bonding situation is more favored. Besides, the photophysical properties of the gold(i) complex were also investigated. This journal is © The Royal Society of Chemistry.

Aravind Kumar Rengan

Department of Biomedical Engineering

Prabusankar Ganesan

Department of Chemistry

M.A. Narayana

M. Vaddamanu

A. Sathyanarayana

K. Siddhant

S. Sugiyama

K. Ozaki

K. Velappan

K. Hisano

O. Tsutsumi

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IIT Hyderabad

Dalton Transactions

A gold(i) 1,2,3-triazolylidene complex featuring the interaction between gold and methine hydrogen

Journal	Data powered by TypesetDalton Transactions
Publisher	Data powered by TypesetRoyal Society of Chemistry
ISSN	14779226