One-pot photocatalytic synthesis of 2-substituted benzimidazoles from 2-nitroanilines with different alcohols by combined redox cyclization reaction using TiO 2-P25 is reported. The reaction, when performed with ethanol, gives 2-methylbenzimidazole as a single product. However, in a mixture of ethanol and water (1:1), it gives both 2-methylbenzimidazole and 1-ethyl-2-methylbenzimidazole. The products have been characterized by Fourier transorm-infrared, 1H NMR, 13CNMR, and gas chromatography-mass spectrometry analysis. TiO 2-P25 behaves as a combined redox photocatalyst by reducing 2-nitroaniline and oxidizing alcohols simultaneously under ultraviolet light. Easy product isolation under mild conditions and good yield make this one-pot synthesis ecofriendly. Copyright © Taylor & Francis Group, LLC.