Ketones 3a-c exhibit syn-face selectivity in borohydride reduction; MNDO and ab initio calculations on model and realistic transition states, respectively, reproduce the preference, but differ on the role of electrostatic and orbital effects.

Faiz Ahmed Khan

Department of Chemistry

G. Mehta

B. Ganguly

J. Chandrasekhar

Indian Institute of Technology Hyderabad (IITH) is a premier institute of science and technology established in 2008. IITH has been consistently ranked in the&nbsp;<a href="https://iith.ac.in/reports/" rel="noopener noreferrer">top 10 institutes</a>&nbsp;in India for Engineering&nbsp;<a href="https://www.nirfindia.org/2021/EngineeringRanking.html" rel="noopener noreferrer" target="_blank">according to NIRF</a>&nbsp;making it one of the most coveted schools for science and technology in the country.

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Journal	Journal of the Chemical Society, Perkin Transactions 1
ISSN	1472779X